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1 article(s) from Jiang, Yang-Ye

Functionalization of N-arylglycine esters: electrocatalytic access to C–C bonds mediated by n-Bu₄NI

Mi-Hai Luo,
Yang-Ye Jiang,
Kun Xu,
Yong-Guo Liu,
Bao-Guo Sun and
Cheng-Chu Zeng

Beilstein J. Org. Chem. 2018, 14, 499–505, doi:10.3762/bjoc.14.35

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Scheme 1: Cross dehydrogenative coupling of N-arylglycine esters with C–H nucleophiles.

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Scheme 2: Electrochemical CDC reaction of 2a and various N-arylglycine esters. Reaction conditions for the in...

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Scheme 3: Scope of 2 using n-Bu₄NI as mediator. Reaction conditions:1a (0.5 mmol), 2 (0.6 mmol), n-Bu₄NI (30 ...

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Scheme 4: Scaling up.

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Scheme 5: Control experiments.

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Scheme 6: A plausible mechanism for the electrocatalytic cross dehydrogenative coupling of N-arylglycine este...

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Published 22 Feb 2018

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Functionalization of N-arylglycine esters: electrocatalytic access to C–C bonds mediated by n-Bu4NI

Functionalization of N-arylglycine esters: electrocatalytic access to C–C bonds mediated by n-Bu₄NI